CATALYTIC OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE AND CYCLOHEXANOL BY TERT-BUTYL HYDROPEROXIDE OVER Ru/OXIDE CATALYSTS

dc.contributor.authorRekkab-Hammoumraoui, Ilhemeen_US
dc.contributor.authorChokchou-Braham, Abderrahimen_US
dc.contributor.authorPiroult-Roy, Laurenceen_US
dc.contributor.authorKappenstein, Carlesen_US
dc.date.accessioned2013-02-26T09:36:38Zen_US
dc.date.available2013-02-26T09:36:38Zen_US
dc.date.issued2011en_US
dc.description.abstractHeterogeneous oxidation of cyclohexane with tertiobutyl hydroperoxide was carried out on Pt/oxide (Al2O3, TiO2 and ZrO2) catalysts in the presence of different solvents (acetic acid and acetonitrile). The catalysts were prepared using Pt(NH3)2(NO2)2 as a precursor and characterized by chemical analysis using the ICP–AES method, XRD, TEM, FTIR and BET surface area determination. The oxidation reaction was carried out at 70°C under atmospheric pressure. The results showed the catalytic performance of Pt/Al2O3 as being very high in terms of turnover frequency.en_US
dc.identifier.urihttps://dspace.univ-tlemcen.dz/handle/112/1477en_US
dc.subjectOxidationen_US
dc.subjectcyclohexaneen_US
dc.subjectplatinumen_US
dc.subjectTBHPen_US
dc.subjectcyclohexanolen_US
dc.subjectcyclohexanoneen_US
dc.titleCATALYTIC OXIDATION OF CYCLOHEXANE TO CYCLOHEXANONE AND CYCLOHEXANOL BY TERT-BUTYL HYDROPEROXIDE OVER Ru/OXIDE CATALYSTSen_US

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