Spectrophotometric Study of Cobalt (II) Chlorocomplexes in Methanol in the Visible Domain

dc.contributor.authorBoulefred, Soumiaen_US
dc.contributor.authorChiboub-Fellah, Abdelghanien_US
dc.contributor.authorChiboub-Fellah, Fatema Zohraen_US
dc.contributor.authorAhmed Khan, Mustayeenen_US
dc.date.accessioned2013-05-02T14:23:03Zen_US
dc.date.available2013-05-02T14:23:03Zen_US
dc.date.issued2011en_US
dc.descriptionADVANCES IN INNOVATIVE MATERIALS AND APPLICATIONS, DOI: 10.4028/www.scientific.net/AMR.324.170, Volume :324, pp. 170-173, 2011.en_US
dc.description.abstractCobalt(II) chlorocomplexes were studied in a polar protic solvent namely methanol at 25°C. The spectrophotometric technique in the visible region was used. The studied equilibrium is: Co2+ + j Cl- CoClj ↔ (j-2)-. Formation of three chlorocomplexes and a structural modification (Oh → Td) were obtained from recorded spectra analysis. The stability of CoCl+ was studied by the graphical method of Kruh and the overall stability constants were calculated with the SIRKO program based on the least-square method. Different models were tested and the model was retained for which the best values are: log β1 = 0.92, log β2 = 1.31 and log β3 = 1.08.en_US
dc.identifier.urihttps://dspace.univ-tlemcen.dz/handle/112/1881en_US
dc.language.isoenen_US
dc.subjectCobalt(II) Chlorocomplexesen_US
dc.subjectSpectrophotometryen_US
dc.subjectStability Constant βJen_US
dc.subjectStructural Modifications OH → TDen_US
dc.titleSpectrophotometric Study of Cobalt (II) Chlorocomplexes in Methanol in the Visible Domainen_US
dc.typeArticleen_US

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