Chiali Baba Ahmed, NouriaNegadi, LatifaMokbel, IlhamAit Kaci, AhmedJose, Jacques2013-04-092013-04-092012-01https://dspace.univ-tlemcen.dz/handle/112/1723The vapour pressures of (sec-butylamine + water), (cyclohexylamine + water) binary mixtures, and of pure sec-butylamine and cyclohexylamine components were measured by means of two static devices at temperatures between 293 (or 273) K and 363 K. The data were correlated with the Antoine equation. From these data, excess Gibbs functions (GE) were calculated for several constant temperatures and fitted to a fourth order Redlich–Kister equation using the Barker’s method. The (cyclohexylamine + water) system shows positive azeotropic behaviour for all investigated temperatures. The two binary mixtures exhibit positive deviations in GE for all investigated temperatures over the whole composition range.en(Vapour + liquid) equilibriaIsoteniscopeAminesWaterExcess Gibbs free energyArticle